P U B L I C A T I O N S

Hill, C. L., "Stable, Self-Assembling, Equilibrating Catalysts for Green Chemistry", Angew. Chem. Int. Ed. 2004, 43, 402-404.

Hill, C. L., "Polyoxometalates: Reactivity", In Comprehensive Coordination Chemistry-II: From Biology to Nanotechnology, Wedd, A. G., Ed. Elsevier Ltd.: Oxford, UK, 2004; Vol. 4, pp 679-759.

Hill, C. L., "Stable, Self-Assembling, Equilibrating Catalysts for Green Chemistry", Angew. Chem. Int. Ed. 2004, 43, 402-404.

Ritorto, M. D.; Anderson, T. M.; Neiwert, W. A.; Hill, C. L., "Decomposition of A-Type Sandwiches. Synthesis and Characterization of New Polyoxometalates Incorporating Multiple d-Electron-Centered Units", Inorg. Chem. 2004, 43, (1), 44-49.

Geletii, Y. V.; Musaev, D. G.; Khavrutskii, L.; Hill, C. L., "Peroxynitrite Reactions with Dimethylsulfide and Dimethylselenide: An Experimental Study". J. Phys. Chem. A 2004, 108, 289-294.

Keita, B.; Mbomekalle, I. M.; Nadjo, L.; Anderson, T. M.; Hill, C. L., "Multi-Iron Wells-Dawson Heteropolytungstates. Electrochemical Probing of Siderophoric Behavior in Sandwich-Type Complexes", Inorg. Chem. 2004, 43, 3257-3263.

Kholdeeva, O. A.; Vanina, M. P.; Timofeeva, M. N.; Maksimovskaya, R. I.; Trubitsina, T. A.; Melgunov, M. S.; Burgina, E. B.; Mrowiec-Bialon, J.; B., J. A.; Hill, C. L., "Co-containing Polyoxometalate-Based Heterogeneous Catalysts for the Selective Aerobic Oxidation of Aldehydes Under Ambient Conditions", J. Catal. 2004, 226, 363-371.

Anderson, T. M.; Neiwert, W. A.; Kirk, M. L.; Piccoli, P. M. B.; Schultz, A. J.; Koetzle, T., F.; Musaev, D. G.; Morokuma, K.; Cao, R.; Hill, C. L.," A Late-Transition Metal Oxo Complex: K₇Na₉[O=Pt^IV(H₂O)L₂], L=[PW₉O₃₄]^9-", Science 2004, 306, 2074-2077.  Article also highlighted in ScienceExpress: www.sciencexpress.org / 25 November 2004 / Page 2/ 10.1126/ science.1104696.  And was noted in many magazines.

Okun, N. M.; Ritorto, M. D.; Anderson, T. M.; Apkarian, R. P.; Hill, C. L., "Polyoxometalates on Cationic Silica Nanoparticles.  Physicochemical Properties of an Electrostatically Bound Multi-Iron Catalyst", Chem Mater. 2004, 16, 2551-2558.

DuBose, D. A.; Blaha, M. D.; Morehouse, D. H.; Okun, N.; Hill, C. L., "Effect of Potential Vesicant Antagonist Drugs on White Blood Cell Metabolic Activity in Human Whole Blood Exposed to 2-Chloroethyl Ethyl Sulfide", J. Medical Chemical Defense 2004, 2, 1-12.

Musaev, D. G.; Morokuma, K.; Geletii, Y. V.; Hill, C. L., "Computational Modeling of Di-Transition-Metal-Substituted γ-Keggin Polyoxometalate Anions. Structural Refinement of the Protonated Divacant Lacunary Silicodecatungstate", Inorg. Chem. 2004, 43, 7702-7708.

Mbomekalle, I. M.; Keita, B.; Nadjo, L.; Hardcastle, K. I.; Hill, C. L.; Anderson, T. M., "Semi-vacant Wells-Dawson anions. Synthesis of tri-tungsten-vacant derivatives and crystallographic studies of [αββα-(Cu^IIOH₂)₂(Cu^II)₂(AsW₁₅(OH₂)₃(OH)O₅₂)₂]^12- ", J. Chem. Soc., Dalton Trans. 2004, 4094-4095

Anderson, T. M.; Neiwert, W. A.; Hardcastle, K. I.; Hill, C. L., "Multi-Iron Silicotungstates: Synthesis, Characterization, and Stability Studies of Polyoxometalate Dimers", Inorg. Chem. 2004, 43, 7353-7358.

Keita, B.; Mbomekalle, I. M.; Lu, Y. W.; Nadjo, L.; Berthet, P.; Anderson, T. M.; Hill, C. L., "Electron Transfer Behavior of Multi-Iron Sandwich-Type Polyoxometalates and electrocatalytic Reduction Reactions", Eur. J. Inorg. Chem. 2004, 3462-3475.

Geletii, Y. V.; Hill, C. L.; Bailey, A. J.; Hardcastle, K. I.; Atalla, R. H.; Weinstock, I. A., "Electron exchange between α-Keggin tungstoaluminates and a well-defined cluster-anion probe for studies in electron transfer", Inorg. Chem. 2005, 44, 8955-8966.

Fang, X.; Anderson, T. M.; Hill, C. L., "Enantiomerically Pure Polytungstates: Chirality Transfer through Zirconium Coordination Centers to Nanosized Inorganic Clusters", Angew. Chem. Int. Ed. 2005, 44, 3540-3544.

Kholdeeva, O. A.; Timofeeva, M. N.; Maksimov, G. M.; Maksimovskaya, R. I.; Neiwert, W. A.; Hill, C. L., "Aerobic Oxidation of Formaldehyde Mediated by a Ce-Containing Polyoxometalate under Mild Conditions", Inorg. Chem. 2005, 44, 666-672.

Mbomekalle, I. M.; Cao, R.; Hardcastle, K. I.; Hill, C. L.; Ammam, M.; Keita, B.; Nadjo, L.; Anderson, T. M., "Synthesis, structural characterization, and electrocatalytic studies of αββα-(Zn^IIOH₂)₂(Fe^III)₂(X₂W₁₅O₅₆)₂^14-  (X = P or As)", C. R. Chimie 2005, 8, (6-7), 1077-1086.

Mbomekalle, I. M.; Lu, Y. W.; Keita, B.; Nadjo, L.; Neiwert, W. A.; Hardcastle, K. I.; Hill, C. L.; Anderson, T. M., "Crystallographic Studies of a Molybdenum-Rich Diarsenotungstate and Reaction of Fe(III) with Its Isomerically Pure a_1- and a_2- Monolacunary Derivatives", Eur. J. Inorg. Chem. 2005, 1547-1551.

Anderson, T. M.; Cao, R.; Neiwert, W. A.; Hardcastle, K. I.; Hill, C. L.; Ammam, M.; Keita, B.; Nadjo, L., "Structural and Electrochemical Studies of Dimerization and Rotational Isomerization in Multi-Iron Silicotungstates", Eur. J. Inorg. Chem. 2005, 1770-1775.

Fang, X.; Anderson, T. M.; Benelli, C.; Hill, C. L., "Polyoxometalate-Supported Y– and Yb^III–Hydroxo/Oxo Clusters from Carbonate-Assisted Hydrolysis", Chem. Eur. J. 2005, 11, (2), 712-718.

Botar, B.; Kögerler, P.; Hill, C. L., "[{(Mo)Mo₅O₂₁(H₂O)₃(SO₄)}₁₂(VO)₃₀(H₂O)₂₀]^36-: A Molecular Quantum Spin Icosidodecahedron", Chem Comm 2005, 25, 3138-3140. (featured cover article).

Botar, B.; Geletii, Y. V.; Köegerler, P.; Musaev, D. G.; Morokuma, K.; Weinstock, I. A.; Hill, C. L., "Asymmetric terminal ligation on substituted sites in a disorder-free Keggin anion, [β-SiFe₂W₁₀O₃₆(OH)₂(H₂O)Cl]^5-", Dalton Trans. 2005, 2017-2021.

Kholdeeva, O. A.; Timofeeva, M. N.; Maksimov, G. M.; Maksimovskaya, R. I.; Rodionova, A. A.; Hill, C. L., "Aerobic Formaldehyde Oxidation under Mild Conditions Mediated by Ce-Containing Polyoxometalates", In Catalysis of Organic Reactions, Sowa, J. R., Jr., Ed. Marcel Dekker, Inc.: New York, 2005; pp 429-433.

Anderson, T. M.; Cao, R.; Slonkina, E.; Hedman, B.; Hodgson, K. O.; Hardcastle, K. I.; Neiwert, W. A.; Wu, S.; Kirk, M. L.; Knottenbelt, S.; Depperman, E. C.; Keita, B.; Nadjo, L.; Musaev, D. G.; Morokuma, K.; Hill, C. L., "A Palladium-Oxo Complex. Stabilization of This Proposed Catalytic Intermediate by an Encapsulating Polytungstate Ligand", J. Am. Chem. Soc. 2005, 127, 11948-11949.

Fang, X.; Anderson, T. M.; Hou, Y.; Hill, C. L., "Sterioisomerism in Polyoxometalates: Structural and Spectroscopic Studies of Bis(malate)-Functionalized Cluster Systems", Chem. Commun. 2005, 5044-5046.

Botar, B.; Kögerler, P.; Müller, A.; Garcia-Serres, R.; Hill, C. L., "Ferrimagnetically ordered nanosized polyoxomolybdate-based cluster spheres", Chem. Commun. 2005, 5621-5623. Selected by the editors as a “Hot Article”. DOI: 10.1039/b512244a

Sundaram, K. M.; Neiwert, W. A.; Hill, C. L.; Weinstock, I. A., "Relative Energies of α- and β-Isomers of Keggin Dodecatungstogallate", Inorg. Chem. 2005, 45, 958-960.

Okun, N. M.; Tarr, J. C.; A., H. D.; Zhang, L.; Hardcastle, K. I.; Hill, C. L., "Highly Reactive Catalysts for Aerobic Thioether Oxidation.  The Fe-substituted Polyoxometalate/hydrogen Dinitrate System, J. Mol. Catal. A. Chem. 2006, 246, 11-17.

Botar, B.; Geletii, Y. V.; Kögerler, P.; Musaev, D. G.; Morokuma, K.; Weinstock, I. A.; Hill, C. L., "True Nature of the Di-iron(III) γ-Keggin Structure in Water: Catalytic Aerobic Oxidation and Chemistry of an Unsymetrical Trimer", J. Am. Chem. Soc. 2006, 128, 1126-1127.

Quiñonero, D.; Wang, Y.; Morokuma, K.; Khavrutskii, L. A.; Botar, B.; Geletii, Y. V.; Hill, C. L.; Musaev, D. G., "The Role of the Central Atom in Structure and Reactivity of Polyoxometalates with Adjacent d-Electron Metal Sites.  Computational and Experimental Studies of γ-[(Xⁿ⁺O₄)Ru^III₂(OH)₂(M_FM)₁₀O₃₂]^(8-n)- for M_FM = Mo and W, and X = Al^III, Si^IV, P^V, and S^VI", J. Phys. Chem. 2006, 110, 170-173.

Hill, C. L.; Anderson, T. M.; Han, J.; Hillesheim, D. A.; Geletii, Y. V.; Okun, N. M.; Cao, R.; Botar, B.; Musaev, D. G.; Morokuma, K., "New complexes and materials for O₂-based oxidations", J. Mol. Catal. A: Chem. 2006, 251, 234-238 (special issue from ADHOC conference edited by A. Berkessel).

Prabhakar, R.; Morokuma, K.; Hill, C. L.; Musaev, D. G., "Insights into the Mechanism of Selective Olefin Epoxidation Catalyzed by [γ-(SiO₄)W₁₀O₃₂H₄]^4-. A Computational Study", Inorg. Chem. 2006, 45, 5703-5709.

Wang, Y.; Zheng, G.; Morokuma, K.; Geletii, Y. V.; Hill, C. L.; Musaev, D. G., "Density Functional Study of the Roles of Chemical Composition of Di-Transition-Metal-Substituted γ-Keggin Polyoxometalate Anions", J. Phys. Chem: B, 2006, 110, (11), 5230-5237. DOI: 10.1021/jp0571978

Botar, B.; Kögerler, P.; Hill, C. L., "A Nanoring-Nanosphere Molecule, Mo₂₁₄V₃₀.  Pushing the Boundaries of Controllable Inorganic Structural Organization at the Molecular Level", J. Am. Chem. Soc. 2006, 128, 5336-5337.

Botar, B.; Geletii, Y. V.; Kögerler, P.; Musaev, D. G.; Morokuma, K.; Weinstock, I. A.; Hill, C. L., "The True Nature of the Di-iron(III) γ-Keggin Structure in Water: Catalytic Aerobic Oxidation and Chemistry of an Unsymmetrical Trimer", J. Am. Chem. Soc. 2006, 128, 11268-11277. DOI: 10.1021/ja063157l

Hill, C. L.; Okun, N. M.; Hillesheim, D. A.; Geletii, Y. V., "Catalysts for Aerobic Decontamination of Chemical Warfare Agents Under Ambient Conditions." In Polymers and Materials for Anti-Terrorism and Homeland Defense, ACS Symposium Series, Reynolds, J. G.; Lawson, G. E., Eds. American Chemical Society: Washington, D.C., 2006 in press.

Geletii, Y. V.; Hill, C. L.; Atalla, R. H.; Weinstock, I. A., "Reduction of O₂ to Superoxide Anion (O₂^-) in Water by Heteropolytungstate Cluster-Anions", J. Am. Chem. Soc. 2006, 128, 10733-17042.

Anderson, T. M.; Fang, X.; Mbomekalle, I. M.; Keita, B.; Nadjo, L.; Hardcastle, K. I.; Farsidjani, A.; Hill, C. L., "Structural and Electrochemical Studies of Dicupric Wells-Dawson Sandwich-Type Complexes" (invited ms for M. T. Pope special issue), J. Cluster Sci. 2006, 17, (2), 183-195.

Han, J. W.; Hardcastle, K. I.; Hill, C. L., "Redox-active coordination polymers from esterified hexavanadate units and divalent metal cations", Eur. J. Inorg. Chem. 2006, (13), 2598-2603.

Botar, B.; Kögerler, P.; Hill, C. L., "Tetrairon and Hexairon Hydroxo/Acetato Clusters Stabilized by Multiple Polyoxometalate Scaffolds. Structures, Magnetic Properties, and Chemistry of a Dimer and a Trimer", Inorg. Chem. 2007, 46, (13), 5398-5403.

Hou, Y.; Fang, X.; Hill, C. L., "Breaking symmetry: spontaneous resolution of a polyoxometalate", Chem. Eur J. 2007, 13, 9442-9447.

Fang, X.; Hill, C. L., "Multiple Reversible Protonation of Polyoxoanion Surfaces: Direct Observation of  Dynamic Sructural Effects from Proton Transfer", Angew. Chem. Int. Ed. 2007, 46, (21), 3877-3880.

Han, J. W.; Hill, C. L., "A coordination network that catalyzes O₂-based oxidations", J. Am. Chem. Soc. 2007, 129, 15094-15095.

Hill, C. L., Foreword, "Polyoxometalates in Catalysis". J. Mol. Catal. A: Chem. Special Issue 2007, 262, (1-2), 1.

Hill, C. L., "Progress and challenges in polyoxometalate-based catalysis and catalytic materials chemistry", In Polyoxometalates in Catalysis, Hill, C. L., Ed. Elsevier: 2007; Vol. J. Mol. Catal. A: Chem, pp 2–6.

Hill, C. L., " Polyoxometalates in Catalysis". Elsevier: 2007 Special Issue; Vol. 262, p 1-242.

Quiñonero, D.; Morokuma, K.; Geletii, Y. V.; Hill, C. L.; Musaev, D. G., "A Density Functional Study of Geometry and Electronic Structures of [(SiO₄)(M^III)₂(OH)₂W₁₀O₃₂]^4-, M = Mo, Ru and Rh", J. Mol. Catal. A: Chem. 2007, 262, (1-2), 227-235.

Cao, R.; Anderson, T. M.; Piccoli, P. M. B.; Schultz, A. J.; Koetzle, T. F.; Geletii, Y. V.; Slonkina, E.; Hedman, B.; Hodgson, K. O.; Hardcastle, K. I.; Fang, X.; Kirk, M. L.; Knottenbelt, S.; Kögerler, P.; Musaev, D. G.; Morokuma, K.; Takahashi, M.; Hill, C. L., "Terminal Gold-oxo Complexes", J. Am. Chem. Soc. 2007, 129, (36), 11118-11133.

Hill, C. L.; Delannoy, L.; Duncan, D. C.; Weinstock, I. A.; Renneke, R. F.; Reiner, R. S.; Atalla, R. H.; Han, J. W.; Hillesheim, D. A.; Cao, R.; Anderson, T. M.; Okun, N. M.; Musaev, D. G.; Geletii, Y. V., "Complex catalysts from self-repairing ensembles to highly reactive air-based oxidation systems", C.R. Chimie 2007, 10, 305-312.

Cao, R.; Han, J. W.; Anderson, T. M.; Hillesheim, D. A.; Kirk, M. L.; Musaev, D. G.; Morokuma, K.; Geletii, Y. V.; Hill, C. L., "Late Transition Metal Oxo Compounds and Open Framework Materials that Catalyze Aerobic Oxidations", Adv. Inorg. Chem. 2008, 60, 245-272 (Chapter 6).

Hill, C. L., "Terminal oxo complexes of the catalytically important noble metals realised", Chem. in Australia 2007, 74, (11), 17-18.

Luo, Z.; Kögerler, P.; Cao, R.; Hakim, I.; Hill, C. L., "Synthesis, structure and magnetism of a new dimeric silicotungstate: K₉Na₂Cu_0.5[≥-Cu₂(H₂O)SiW₈O₃₁]₂•38H₂O", Dalton Trans. 2008, 54-58.

Geletii, Y. V.; Botar, B.; Kögerler, P.; Hillesheim, D. A.; Musaev, D. G.; Hill, C. L., An All-Inorganic, Stable, and Highly Active Tetraruthenium Homogeneous Catalyst for Water Oxidation. Angew. Chem. Int. Ed. 2008, 47, 3896-3899. Selected as the VIP Article by the reviewers and editor.  Published online 3/20/08 DOI: 10.1002/anie.200705652

Kuznetsov, A. E.; Geletii, Y. V. Hill, C. L.; Morokuma, K.; Musaev, D. G. “On the Mechanism of the Divanadium-substituted Polyoxotungstate [γ-1,2-H₂SiV₂W₁₀O₄₀]^4- Catalyzed Olefin Epoxidation by H₂O₂: A Computational Study.” Inorganic Chemistry, 2008, in submission.

Song, J.; Hillesheim, D. A.; Han, J.-W.; Cao, R.; Geletii, Y. V.; Hill, C. L. “Organic esters of {V6O19}; synthons that detect and catalytically decontaminate using air” Defense Technical Information Center (DTIC, online journal), 2008.

Merca, A.; Bögge, H.; Schmidtmann, M.; Zhou, Y.; Sarker, M. K.; Hill, C. L.; Müller, A., "Cation behavior at an artificial cell interface; binding and transport distinguished by ion hydration energetics and size", Chem. Commun. 2008, 948-950. Highlighted on Chemical Science website (www.rsc.org/ChemicalScience) and Chemistry World (www.rsc.org/ChemistryWorld)

Prabhakar, R.; Morokuma, K.; Geletii, Y. V.; Hill, C. L.; Musaev, D. G., "Insights into the Mechanism of H₂O₂-based Olefin Epoxidation Catalyzed by the Lacunary [γ-(SiO₄)W₁₀O₃₂H₄]^4- and di-V-substituted-γ-Keggin [γ-1,2-H₂SiV₂W₁₀O₄₀]^4- Polyoxometalates. A Computational Study", In Computational Modeling for Homogenous and Enzymatic Catalysis, Morokuma, K.; Musaev, D. G., Eds. Wiley: New York, 2008, pp 215-230.

Luo, Z.; Kögerler, P.; Cao, R.; Hill, C. L. “Synthesis, structure and magnetism of a one-dimensional silicotungstate array: K₃H₄Cu_0.5{Cu[Cu_7.5Si₂W₁₆O₆₀(H₂O)₄(OH)₄]₂}· 9H₂O” Polyhedron, 2008, 28, 215-220.

Hill, C. L. “Confirmation of the Improbable” Nature, 2008, 455, 1045-1047.

Cao, R.; Anderson, T. M.; Hardcastle, K. I.; Hill, C. L. “Synthesis of a terminal Pd-oxo complex, K₁₀Na₃[Pd^IV(O)(OH) P₂W₁₉O₆₉(OH₂)]•16H₂O” Inorganic Syntheses, 2008, submitted.

Cao, R.; Anderson, T. M.; Hillesheim, D. A.; Kögerler, P.;  Hardcastle, K. I.; Hill, C. L. “Platinum-Containing Polyoxometalates”, Angew. Chem. Int. Ed. 2008, 47, 9380-9382.

Kuznetsov, A. E.; Geletii, Y. V.; Hill, C. L.; Morokuma, K.; Musaev, D. G. “Mechanism of O₂-based Oxidation of the Diruthenium-substituted γ-Keggin Polyoxotungstate [γ-Ru^III₂(H₂O)₂H₂SiW₁₀O₃₈]^4-: Comparison with the “Blue Dimer” Water Oxidation Catalyst” J. Am. Chem. Soc. 2009, 131, ASAP.

Cao, R.; Ma, H.; Geletii, Y. V.; Hardcastle, K. I.; Hill, C. L. “A Structurally Characterized Iridium(III)-Containing Polytungstate and Catalytic Water Oxidation Activity” Inorg. Chem. 2009, submitted.

Besson, C.; Musaev, D. G.; Lahootun, V.; Cao, R.; Chamoreau, L.-M.; Villaneau, R.; Villan, F.; Thouvenot, R.; Geletii, Y. V.; Hill, C. L.; Proust, A. “Vicinal di-nitridoruthenium substituted polyoxometalates, γ-[XW₁₀O₃₈{RuN}₂]^6- (X=Si or Ge)” Chem., Eur. J. 2009, submitted.

Luo, Z.; Kögerler, P.; Cao, R.; Hill, C. L. “Synthesis, structure and magnetism of a polyoxometalate with coordinatively unsaturated d-electron-transition metal centers” Inorg. Chem. 2009, submitted.

Cao, R.; Anderson, T. M.; Hardcastle, K. I.; Musaev, D. G.; Hill. C. L. “A Dinuclear Terminal Palladium-oxo Complex and Oxo Transfer from Palladium” J. Am. Chem. Soc. 2008, 129, submitted.