Emory University The Craig Hill Research Group

Publications by the Craig L. Hill Research Group

Last Updated: 03/08/2016

 The following is an incomplete list of publications between 2010 and March 2016. 

 

  • Liu, Y. P.; Zhao, S. F.; Guo, S. X.; Bond A. M.; Zhang, J.; Zhu, G.; Geletii, Y. V.; Hill, C. L. “Electrooxidation of Ethanol and Methanol Using the Molecular Catalyst [{Ru4O4(OH)2(H2O)4}(γ-SiW10O36)2]10−J. Am. Chem. Soc., 2016, 138, 2617-2628.  DOI: 10.1021/jacs.5b11408

  • Guo, W.; Lv, H.; Bacsa, J.; Gao, Y.; Lee, J. S.; Hill, C. L. “Syntheses, Structural Characterization and Catalytic Properties of Di- and Trinickel Polyoxometalates” Inorg. Chem. 2016, 55, 461-466.  DOI:10.1021/acs.inorgchem.5b01935

  • Kim, M.; Weinstock, I. A.; Geletii, Y. V.; Hill, C. L. “Oxidation of Reduced Keggin Heteropoly tungstates by Dioxygen in Water Catalyzed by Cu(II)” ACS Catal. 2015, 5, 7048-7054.  DOI: 10.1021/acscatal.5b01771

  • Guo, W.; Bacsa, J.; van Leusen, J.; Sullivan, K. P.; Lv, H.; Kögerler, P.; Hill, C. L. “A Layered Manganese(IV)-Containing Heteropolyvanadate with a 1:14 Stoichiometry” Inorg. Chem.2015, 54, 10604-10609. DOI:10.1021/acs.inorgchem.5b01387

  • Fielden, J; Sumliner, J. M.; Han, N.; Geletii, Y. V.; Xiang, X.; Musaev, D. G.; Lian, T.; Hill, C. L. “Water Splitting with Polyoxometalate-Treated Photoanodes: Enhancing Performance through Sensitizer Design” Chem. Sci., 2015, 6, 5531-5543.  DOI: 10.1039/c5sc01439e

  • Kaledin, A. L.; Lian, T.; Hill, C. L.; Musaev, D. G. “A Hybrid Quantum Mechanical Approach: Intimate Details of Electron Transfer Between Type I CdSe/ZnS Quantum Dots and an Anthraquinone Molecule” J. Phys. Chem, B., 2015, 119, 7651-7658. DOI:10.1021/jp511935z

  • Lv, H.; Chi, Y.; van Leusen, J.; Kögerler, P.; Chen, Z.; Bacsa, J.; Guo, W.; Lian, T.Q; Hill, C. L. “[{Ni4(OH)3AsO4}4(B-α-PW9O34)4]28- a New Polyoxometalate Structural Family with Catalytic Hydrogen Evolution Activity” Chem. Eur. J. 2015, 21, 17363-17370.  DOI: 10.1002/chem.20150301

  • Lauinger, S. M.; Sumliner, J. M.; Yin, Q.; Xu, Z.; Liang, G.; Glass, E. N.; Lian, T.; Hill, C. L. “Enhanced Stability of Immobilized Polyoxometalates on TiO2 Nanoparticles and Nanoporous Films for Robust, Light-Induced Water Oxidation” Chem. Mater. 2015, 27, 5886-5891.    DOI:10.1021/acs.chemmater.5b01248

  • Hibberd, A. M.; Doan, H. Q.; Glass, E. N.; de Groot, F. M. H.; Hill, C. L.; Cuk, T.  “Co Polyoxometalates and a Co3O4 thin film investigated by L-Edge Absorption Spectroscopy” J. Phys. Chem. C. 2015, 119, 4173-4179.  DOI: 10.1021/jp5124037

  • Yin, P.; Zhang, Z.-M.; Lv, H.; Li, T.; Haso, F.; Hu, L.; Zhang, B.; Bacsa, J.; Wei, Y.; Gao, Y.; Hou, Y.; Li, Y.-G.; Hill, C. L.; Wang, E.-N.; Liu, T. “Chiral Recognition and Selection during the Self-Assembly Process of Protein-Mimic Macroanions” Nature Commun., 2015, 6DOI: 10.1038/ncomms7475

  • Zhao, C.; Glass, E. N.; Chica, B.; Musaev, D. G.; Sumliner, J. M.; Dyer, R. B.; Lian, T.; Hill, C. L. “All-Inorganic Networks and Tetramer Based on Tin(II)-ContainingPolyoxometalates: Tuning Structural and Spectral Properties with Lone-Pairs” J. Am. Chem. Soc. 2014, 136, 12085-12091.  DOI: org/10.1021/ja5060127

  • Sumliner, J. M.; Vickers, J. W.; Lv, H.; Geletii, Y. V.; Hill, C. L. “Polyoxometalate Water Oxidation Catalytic Systems” In “Molecular Water Oxidation Catalysts”, Chapter 11, Llobet, A. Ed.; Wiley: New York, 2014, pp. 211-231. DOI: 10.1002/9781118698648.ch11
  • Lv, H.; Guo, W.; Wu, K.; Geletii, Y. V.; Chen, Z.; Lauinger, S. M.; Bacsa, J.; Musaev, D. G.; Lian, T.; Hill, C. L. “A Nobel-Metal-Free, Tetra-nickel-containing Polyoxotungstate Catalyst for the Efficient Photocatalytic Hydrogen Evolution” J. Am. Chem. Soc. 2014, 136, 14015-14018.  DOI: org/10.1021/ja5084078
  • Zhao, C.; Glass, E. N.; Chica, B.; Musaev, D. G.; Sumliner, J. M.; Dyer, R. B.; Lian, T.; Hill, C. L. “All-Inorganic Networks and Tetramer Based on Tin(II)-Containing Polyoxometalates: Tuning Structural and Spectral Properties with Lone-Pairs” J. Am. Chem. Soc. 2014, 136, 12085-12091.  DOI: org/10.1021/ja5060127
  • Glass, E. N.; Fielden, J.; Kaledin, A. L.; Musaev, D. G.; Lian, T.; Hill, C. L. “Extending Metal-to-Polyoxometalate Charge Transfer Lifetimes: The Effect of Heterometal Location” Chem.-Eur. J., 2014, 20(15), 4297-4307. DOI: 10.1002/chem.201304119
  • Sumliner, J. M.; Lv, H.; Fielden, J.; Geletii, Y. V.; Hill, C. L. “Polyoxometalate multi-electron transfer catalytic systems for water splitting”, Eur. J. Inorg. Chem. 2014, 4, 635-644 (Invited review). 10.1002/ejic.201301573
  • Vickers, J. W.; Sumliner, J. M.; Lv, H.; Morris, M.; Geletii, Y. V.; Hill, C. L. “Collecting meaningful early-time kinetic data in homogeneous catalytic water oxidation with a sacrificial oxidant” Physics Chemistry Chemical Physics, 2014, 16, 11942-11949 (Invited paper) DOI:10.1039/c3cp55406f
  • Zhao, C.; Glass, E. N.; Sumliner, J. M.; Bacsa, J.; Kim D. T.; Guo, W.; Hill, C. L. “Complexation of Metal Carbonyl Units with [α-PW11O39]7- and [α2-P2W17O61]10-: Insights into the Chiral “Twisted sandwich” Dimeric Structures” Dalton Transactions, 2014, 43 4040-4047. DOI: 10.1039/c3dt53374c
  • Guo, W., Luo, Z., Lv, H., Hill, C.L. “Aerobic Oxidation of Formaldehyde Catalyzed by Polyvanadotungstates” ACS Catalysis 2014, 4, 1151-1161. DOI: 10.1021/cs5000763
  • Yin, P.; Zhang, Z. M.; Li, T.; Hu, L.; Haso, F.; Zhang, B.; Hou, Y.; Hill, C. L.; Wang, E.-N.; Liu, T. "Chiral Recognition and Chiral Selection during the Self-Assembly Process of Protein-Mimic Macroanions" Nature Commun., 2015, 6(1-8), 6475. DOI: 10.1038/ncomms7475 |www.nature.com/naturecommunications
  • Guo, S.-X.; Lee, C.-Y.; Zhang, J.; Bond, A.; Geletii, Y. V.; Hill, C. L. “Mediator enhanced water oxidation using Rb4[RuII(bpy)3]5[{RuIII4O4(OH)2(H2O)4}(γ-SiW10O36)2] film modified electrodes” Inorg. Chem. 2014, 53, 7561-7570. DOI: 10.1021/ic500878w
  • Wu, K; Chen, Z.; Lv, H.; Zhu, H.; Hill, C. L.; Lian, T. “Hole Removal Rate Limits Photo-driven H2 Generation Efficiency in CdS-Pt and CdSe/CdS-Pt Semiconductor Nanorod-metal tip Heterostructures” J. Am. Chem. Soc. 2014, 136, 7708-7716. DOI: 10.1021/ja5023893
  • Lv, H.; Song, J.; Geletii, Y. V.; Vickers, J. W.; Sumliner, J. M.; Musaev, D. G.; Kögerler, P.; Zhuk, P.; Bacsa, J.; Zhu, G.; Hill, C. L. “An Exceptionally Fast Homogeneous Carbon-Free Cobalt-Based-Water Oxidation Catalyst” J. Am. Chem. Soc. 2014, 136, 9268-9271. DOI: 10.1021/ja5045488
  • Luo, Z.; Guo, W.; Lv, H.; Hill, C. L. “Catalytic Conversion” CBRNe World, 2014, April issue, 56-58. This publication was reviewed and edited but not peer-reviewed.
  • Vickers, J. W.; Sumliner, J. M.; Lv, H.; Geletii, Y. V.; Hill, C. L. “Importance of buffer in the design and study of solar fuel production systems” American Chemical Society, Division of Energy & Fuels (2014), 59(1), 162-163. This publication is not peer-reviewed.
  • Vickers, J. W.; Sumliner, J. M. Geletii, Y. V.; Morris, M.; Hill, C. L. “Modular system for fast quantification of kinetics and oxygen yield of homogeneous water oxidation catalysts” American Chemical Society, Division of Energy & Fuels (2014), 59(1), 673-674. This publication is not peer-reviewed.
  • Kaledin, A. L.; Lian, T.; Hill, C. L.; Musaev, D. G. “An infinite order discrete variable representation of an effective mass Hamiltonian: Application to exciton wavefunctions in quantum confined nanostructures”, J. Chem. Theory Comput., 2014, 10, 3409-3416. DOI: 10.1021/ct500280j
  • Lv, H.; Guo, W.; Wu, K.; Geletii, Y. V.; Chen, Z.; Lauinger, S. M.; Bacsa, J.; Musaev, D. G.; Lian, T.; Hill, C. L. “A Nobel-Metal-Free, Tetra-nickel-containing Polyoxotungstate Catalyst for the Efficient Photocatalytic Hydrogen Evolution” J. Am.  Chem. Soc. 2014, 136, 14015-14018. DOI:org/10.1021/ja5084078
  • Guo, S.-X.; Liu, Y.; Lee, C.-Y.; Bond, A. M.; Zhang, J.; Geletii, Y. V.; Hill, C. L. “Graphene-Supported [{Ru4O4(OH)2(H2O)4}γ-SiW10O36)2]10- for Highly Efficient Electrocatalytic Water Oxidation” Energy Environ. Sci. 2013, 6, 2654-2663. DOI: 10.1039/C3EE41892H
  • Faunce, T.; Styring, S.; Wasielewski, M. R.; Brudvig, G. W.; Rutherford, A. W.; Messinger, J.; Lee, A. F.; Hill, C. L.; deGroot, H.; Fontecave, M.; MacFarlane, D. R.; Hankamer, B.; Nocera, D. G.; Tiede, D. M.; Dau, H.; Hillier, W.; Wang, L.; Amal, R. “Artifical photosynthesis as a frontier technology for energy sustainability” Energy Environ. Sci. 2013, 6, 1074-1076. DOI: 10.1039/C3EE40534F
  • Zhao, C.; Kambara, C. S.; Yang, Y.; Kaledin, A. L.; Musaev, D.G.; Lian, T.; Hill, C.L. “Synthesis, Structures, and Photochemistry of Tricarbonyl Metal Polyoxoanion Complexes, [X2W20O70{M(CO)3}2]12- (X = Sb, Bi and M = Re, Mn)” Inorg. Chem. 2013, 52 (2), 671-678. DOI: 10.1021/ic301766b
  • Liu, X.; An, H.; Chen, Z.; Zhang, H.; Hu, Y.; Zhu, G.; Geletii, Y. V.; Hill, C. L. “In situ Recrystallization Based on Polyoxometalates: From 0D Architectures to 2D Inorganic-Organic Hybrids” Eur. J. Inorg. Chem. 2013, 10-11, 1827–1834.
  • Kaledin, A. L.; van Duin, A. C. T.; Hill, C. L.; Musaev, D. G. “Parameterization of Reactive Force Field: Dynamics of the [HxNb6O19](8-x) Lindqvist Polyoxoanion in Bulk Water”, J. Phys. Chem. A, 2013, 117 (32), 6967-6974. DOI: 10.1021/jp312033p
  • Lv, H.; Song, J.; Geletii, Y.V.; Guo, W.; Basca, J.; Hill, C. L. “A New Hexanuclear Cobalt(II) Cluster Incorporated in a Banana-shaped Tungstovanadate: [(Co(OH2)Co2VW9O34)2(VW6O26)]17- ” Eur. J. Inorg. Chem., 2013, 10-11, 1720-1725. DOI: 10.1002/ejic.201201130
  • Matt, B.; Xiang, X.; Kaledin, A. L.; Han, N.; Moussa, J.; Amouri, H.; Alves, S.; Hill, C. L.; Lian, T.; Musaev, D. G.; Izzet, G.; Proust, A. “Long lived charge separation in iridium(III)-photosensitized polyoxometalates: synthesis, photophysical and computational studies of organometallic-redox tunable oxide assemblies” Chem. Sci., 2013, 4, 1737-1745. DOI: 10.1039/C3SC21998D
  • Xiang, X.; Fielden, J.; Rodriguez, W.; Zhuangqun, N.; Zhang, N.; Luo, Z.; Musaev, D.G.; Lian, T.; Hill, C.L. “Electron Transfer Dynamics in Semiconductor-Chromophore-Polyoxometalate Catalyst Photoanodes” J. Phys. Chem. C, 2013, 117 (2), 918-926.
  • Hill, C. L.; Kholdeeva, O. A. “Selective Liquid Phase Oxidations in the Presence of Supported Polyoxometalates”, Clerici, M. G. and Kholdeeva, O. A., Eds.; John Wiley & Sons, Inc., 2013 pages 263-319. DOI: 10.1002/9781118356760.ch6
  • Lv, H.; Rudd, J. A.; Zhuk, P. F.; Lee J. Y.; Constable E. C.; Housecroft, C. E.; Hill, C. L.; Musaev, D. G.; Geletii, Y. V. “Bis(4'-(4-pyridyl)-2,2':6',2"-terpyridine)ruthenium(II) complexes and their N-alkylated derivatives in catalytic light-driven water oxidation”, RSC Advances 2013, 3, 20647-20654.
  • Liu, Y.; Guo, S.-X.; Bond, A. M.; Zhang, J.; Geletii, Y. V.; Hill, C. L. “Voltammetric Determination of the Reversible Potentials for [{Ru4O4(OH)2(H2O)4}(γ-SiW10O36)2]10- over the pH range of 2 to 12: Electrolyte Dependence and Implications for Water Oxidation Catalysis” Inorg. Chem. 2013, 52, 11986–11996.
  • Lv, H.; Song, J.; Zhu, H.; Geletii, Y. V.; Bacsa, J.; Zhao, C; Lian, T.; Musaev, D. G.; Hill, C. L. “Visible-Light-Driven Hydrogen Evolution from Water Using a Noble-Metal-Free Polyoxometalate Catalyst” J. Catal. 2013, 307, 48-54.
  • Zhao, C.; Rodríguez-Córdoba, W.; Kaledin, A. L.; Yang, Ye.; Geletii, Y. V.; Lian, T.; Musaev, D. G.; Hill, C. L. “An Inorganic Chromophore Based on a Molecular Oxide Supported Metal Carbonyl Cluster: [P2W17O61{Re(CO)3}3{ORb(H2O)}(μ3-OH)]9–” Inorg. Chem. 2013, 52, 13490-13495. DOI: 10.1021/ic4018823
  • Vickers, J. W.; Lv, H.; Sumliner, J. M.; Zhu, G.; Luo, Z.; Musaev, D. G.; Geletii, Y. V.; Hill, C. L. “Differentiating homogeneous and heterogeneous water oxidation catalysis: confirmation that [Co4(H2O)2(α-PW9O34)2]10- is a molecular water oxidation catalyst.” J. Am. Chem. Soc., 2013, 135, 14110−14118. DOI: 10.1021/ja4024868
  • Li, D.; Song, J.; Zhang, B.; Yin, P.; Roberts, J. E.; Hill, C. L.; Liu, T. “Cation Translocation around Polyoxometalate-organic Hybrid Clusters Regulated by Electrostatic and Cation-π Interactions” MMMMM. 2013, 00, 000 submitted.
  • Guo, W.; Luo, Z.; Song, J.; Zhu, G.; Zhao, C.; Lv, H.; Vickers, J. W.; Geletii, Y. V.; Musaev, D. G.; Hill, C. L. "Multi-electron transfer catalysts for air-based organic oxidations and water oxidation" in "Complexity in Chemistry and Beyond: Interplay Theory and Experiment" Hill, C. L. and D. G. Musaev, Eds. Springer, 2012.
  • Lee, C.-Y.; Guo, S.-X.; Murphy, A. F.; McCormac, T.; Zhang, J.; Bond, A. M.; Zhu, G.; Hill, C. L.; Geletii, Y. V. “Detailed Electrochemical Studies of the Tetraruthenium Polyoxometalate Water Oxidation Catalyst in Acidic Media: Identification of an Extended Oxidation Series using Fourier Transformed Alternating Current Voltammetry” Inorg. Chem. 2012, 51, 11521−11532. DOI: 10.1021/ic301370y
  • Huang, Z.; Geletii, Y. V.; Musaev, D. G.; Hill, C. L.; Lian T. “Spectroscopic Studies of Light-driven Water Oxidation Catalyzed by Polyoxometalates”, Industrial & Engineering Chemistry Research, 2012, 51 (37), 11850-11859. DOI- 10.1021/ie202950h
  • Zhu, H.; Song, N.; Lv, H.; Hill, C. L.; Lian, T. “Near unity quantum yield of light-driven redox mediator reduction and efficient H2 generation using colloidal nanorod heterostructures” J. Am. Chem. Soc., 2012, 134, 11701-11708
  • Zhu, G.; Song, J.; Geletii, Y. V.; Zhao, C.; Hill, C. L. “Di- and Tri-Cobalt Silicotungstates: Synthesis, Characterization, and Stability Studies” Inorg. Chem., 2013, 52 (2), pp 1018–1024. DOI: 10.1021/ic302279m
  • Zhu, G.; Geletii, Y. V.; Zhao, C.; Musaev, D. G.; Hill, C. L. “A Dodecanuclear Zn(II) Cluster Sandwiched by Polyoxometalate Ligands” (Special Issue on Polyoxometalates) Dalton Transactions, 2012, 41 (33), 9908-9913.
  • Vickers, J.; Lv, H.; Zhuk, P. F.; Geletii, Y. V.; Hill, C. L. “Multi-Electron-Transfer Catalysts Needed for Artificial Photosynthesis”, Proceedings of the Materials Research Society, (peer reviewed proceedings), 2012, MRS Proceedings, 1387, mrsf11-1387-e02-01 doi:10.1557/opl.2012.896. 
  • Huang, Z.; Lin Y.; Xiang X.; Rodríguez-Córdoba, W.; McDonald, K. J.; Hagen K. S.; Choi, K.-S.; Brunschwig, B. S.; Musaev, D. G; Hill, C. L.; Wang D.; Lian, T.; “In Situ Probe of Photocarrier Dynamics in Water-splitting Hematite (α-Fe2O3) Electrodes”, Energy Environ. Sci. 2012, 5, 8923-8926.
  • Kaledin, A.L.; Lian, T.; Hill, C. L.; Musaev, D. G. “Structural modification of TiO2 surfaces in bulk water and binding motives of a functionalized C60 on TiO2 anatase and rutile surfaces in vacuo and in water: Molecular dynamics studies ” J. Phys. Chem. C, 2012, 116 (39), 20937-20948.
  • Lv, H.; Geletii, Y. V.; Zhao, C.; Vickers, J. W.; Zhu, G.; Luo, Z.; Song, J.; Lian, T.; Musaev, D. G.; Hill C. L. "Polyoxometalate Water Oxidation Catalysts and the Production of Green Fuel" Chem. Soc. Rev. 2012, 41, 7572-7589. Direct Link
  • Zhu, G.; Geletii, Y. V.; Zhao, C.; Musaev, D. G.; Song, J.; Hill, C. L. " A Dodecanuclear Zn(II) cluster Sandwiched by Polyoxometalate Ligands" Dalton Trans. 2012, 41, 9908-9913
  • Zhu, G.; Glass, E. N.; Zhao, C.; Lv, H.; Vickers, J. W.; Geletii, Y. V.; Musaev, D. G.; Song, J.; Hill, C. L. "A Nickel Containing Polyoxometalate Water Oxidation Catalyst" Dalton Trans. 2012, 41, 13043-13049.
  • O'Halloran, K. P.; Zhao, C.; Ando, N. S.; Schultz, A. J.; Koetzle, T. F.; Piccoli, P. M. B.; Hedman, B.; Hodgson, K. O.; Bobyr, E.; Kirk, M. L.; Knottenbelt, S.; Depperman, E. C.; Stein, B.; Anderson, T. M.; Cao, R.; Geletii, Y. V.; Hardcastle, K. I.; Musaev, D. G.; Neiwert, W. A.; Fang, X.; Morokuma, K.; Wu, S.; Kogerler, P.; Hill, C. L. "Revisiting the Polyoxometalate-Based Late-Transition-Metal-Oxo Complexes: The "Oxo Wall" Stands" Inorg. Chem. 2012, 51, 7025-7031.
  • Huang, Z.; Luo, Z.; Geletii, Y. V.; Vickers, J. W.; Yin, Q.; Wu, D.; Hou, Y.; Ding, Y.; Musaev, D. G.; Hill, C. L.; Lian, T. “Efficient Light-Driven Carbon-Free Cobalt-Based Molecular Catalyst for Water Oxidation” J. Am. Chem. Soc. 2011, 133, 2068–2071.
  • Geletii, Y. V.; Yin, Q.; Hou, Y.; Huang, Z.; Ma, H.; Song, J.; Besson, C.; Luo, Z.; Cao, R.; O’Halloran, K. P.; Zhu, G.; Zhao, C.; Vickers, J. W.; Ding, Y.; Mohebbi, S.; Kuznetsov, A. E.; Musaev, D. G.; Lian, T.; Hill, C. L. “Polyoxometalates in the Design of Effective and Tunable Water Oxidation Catalysts” Israel J. Chem. 2011, 51, 238-246.
  • Li, D.; Song, J.; Yin, P.; Simotwo, S.; Bassler, A. J.; Aung, Y.; Roberts, J. E.; Hardcastle, K. I.; Hill, C. L.; Liu, T. “Inorganic-Organic Hybrid Vesicles with Counterion- and pH-Controlled Fluorescent Properties” J. Am. Chem. Soc. 2011, 133, 14010-14016. 10.1021/ja204034g
  • Luo, Z.; Geletii, Y. V.; Hillesheim, D. A.; Wang, Y.; Hill, C. L. “Mechanistic Studies of O2-based Sulfoxidations Catalyzed by NOx/Br Systems” ACS Catalysis, 2011, 1, 1364-1370. 10.1021/cs2003643
  • Zhu, G.; Lv, H.; Vickers, J. W.; Geletii, Y. V.; Luo, Z.; Song, J.; Huang, Z.; Musaev, D. G.; Hill, C. L. “Structural and mechanistic studies of tunable, stable, fast multi-cobalt water oxidation catalysts”, Proceedings of SPIE, 2011, 8109 (Solar Hydrogen and Nanotechnology VI), 81090A-81090A-6.
  • Zhu, G.; Geletii, Y. V.; Kögerler, P.; Schilder, H.; Song, J.; Lense, S.; Zhao, C.; Hardcastle, K. I.; Musaev, D. G.; Hill, C. L. “Water Oxidation Catalyzed by a New Tetracobalt-Substituted Polyoxometalate Complex: [{Co4(µ-OH)(H2O)3}(Si2W19O70)]11–” Dalton Transactions, 2012, 41, 2084-2090.
  • Zhao, C.; Huang, Z.; Rodríguez-Córdoba, W.; Kambara, C. S.; O’Halloran, K. P.; Hardcastle, K. I.; Musaev, D. G.; Lian, T.; Hill, C. L. “Synthesis and Characterization of a Metal-to-Polyoxometalate Charge Transfer Molecular Chromophore” J. Am. Chem. Soc. 2011, 133, 20134-0137.
  • Kuznetsov, A. E.; Geletii, Y. V.; Hill, C. L.; Morokuma, K.; Musaev, D. G. “The role of the heteroatom (X = SiIV, PV, and SVI) on the reactivity of {γ-[(H2O)RuIII(μ-OH)2RuIII(H2O)][Xn+W10O36]}(8-n)- with the O2 molecule” Theor. Chem. Acc. 2011, 130, 197-207.
  • Huang, Z.; Geletii, Y. V.; Wu, D.; Anfuso, C. L.; Musaev, D. G.; Hill, C. L.; Lian, T. “Interfacial charge transfer dynamics in TiO2-Sensitizer-Ru4POM photocatalytic systems for water oxidation”, SPIE proceedings, 2011, 8109 (Solar Hydrogen and Nanotechnology VI), 810903-810903-10.
  • Zhao, C.; Huang, Z,; Rodriguez-Cordoba, W.; Kambara, C. S.; O'Halloran, K. P.; Hardcastle, K. I.; Musaev, D. G.; Lian, T.; Hill, C. L. "Synthesis and Characterization of a Metal-to-Polyoxometalate Charge Transfer Molecular Chromophore" J. Am. Chem. Soc. 2011, 133, 20134-20137
  • Song, J.; Luo, Z.; Britt, D. K.; Furukawa, H.; Yaghi, O. M.; Hardcastle, K. I.; Hill, C. L. "A Multiunit Catalyst with Synergistic Stability and Reactivity: a Polyoxometalate-Metal Organic Framework for Aerobic Decontamination" J. Am. Chem. Soc2011, 133, 16839
  • Luo, Z.; Geletii, Y. V.; Hillesheim, D. A.; Wang, Y.; Hill, C. L. "Mechanistic Studies of O2-Based Sulfoxidations Catalyzed by NOx/Br Systems" ACS Catal. 2011, 1, 1364-1370 
  • Cao, R.; O’Halloran, K. P.; Hillesheim, D. A.; Lense, S.; Hardcastle, K. I.; Hill, C. L. “Controlled Synthesis of a Functionalized Polytungstate Ligand and a {MaMbMc(PW9)2} Sandwich Complex” CrystEngComm. 2011, 13, 738-740.
  • Quiñonero, D.; Kaledin, A. L.; Kuznetsov, A. E.; Geletii, Y. V.; Besson, C.; Hill, C. L.; Musaev, D. G. “Computational Studies of the Geometry and Electronic Structure of an All-Inorganic and Homogeneous Tetra-Ru-Polyoxotungstate Catalyst for Water Oxidation and Its Four One-Electron Oxidized Forms” J. Phys. Chem., A. 2010, 114, 535-542.
  • Kaledin, A. L.; Huang, Z.; Geletii, Y. V.; Lian, T.; Hill, C. L.; Musaev, D. G. “Insights into photoinduced electron transfer between [Ru(bpy)3]2+ and S2O82- in water: computational and experimental studies, J. Phys. Chem. A. 2010, 114, 73-80.
  • Cao, R.; O’Halloran, K.; Hillesheim, D. A.; Hardcastle, K. I.; Hill, C. L. “Mono-substituted Keggin, Wells-Dawson and {P2W21}-Type Polyoxometalates without Positional Disorder, CrystEngComm, 2010, 12, 1518-1525, DOI:10.1039/b919934a
  • Fang, X.; Speldrich, M.; Schilder, H.; Cao, R.; O’Halloran, K.; Hill, C. L.; Kögerler, P. “Switching slow relaxation in a MnIII3MnIV cluster: an example of grafting single-molecule magnets onto polyoxometalates” Chem. Commun. 2010, 46, 2760-2762.
  • Besson, C.; Huang, Z.; Geletii, Y. V.; Lense, S.; Hardcastle, K. I.; Musaev, D. G.; Lian, D. G.; Lian, T.; Proust, A.; Hill, C. L. “Cs9[(γ PW10O36)2Ru4O5(OH)(H2O)4], a new all-inorganic, soluble catalyst for the efficient visible-light-driven oxidation of water” Chem. Commun. 2010, 46, 2784-2786.
  • Yin, Q.; Tan, J. M.; Besson, C.; Geletii, Y. V.; Musaev, D. G.; Kuznetsov, A. E.; Luo, Z.; Hardcastle, K. I.; Hill, C. L. “A Fast Soluble Carbon-Free Molecular Catalyst Based on Abundant Metals” Science, 2010, 328, 342-345, DOI: 10.1126/science.1185372
  • Hou, Y.; Xu, L.; Cichon, M. J.; Lense, S.; Hardcastle, K. I.; Hill, C. L. “A New Family of Sandwich-Type Polytungstophosphates Containing Two Types of Metals in the Central Belt: M’2M2(PW9O34)212- (M’ = Na or Li, M = Mn2+, Co2+, Ni2+, Zn2+)” Inorg. Chem., 2010, 49 (9), 4125-4132.
  • Kaledin, A. L.; Huang, Z.; Yin, Q.; Dunphy, E. L.; Constable, E. C.; Geletii, Y. V.; Lian, T.; Hill, C. L.; Musaev, D. G. “Insights into Photoinduced Electron Transfer Between [Ru(mptpy)2]4+ (mptpy = 4′(4-methylpyridinio)-2,2′:6′,2′′-terpyridine) and [S2O8]2-: Computational and Experimental Studies” J. Phys. Chem. A. 2010, 114, 6284–6297.
  • Kuznetsov, A. E.; Geletii, Y. V.; Hill, C. L.; Musaev, D. G. “Insights into the mechanism of O2 formation and release from the Mn4O4L6 “Cubane” cluster” J. Phys. Chem. A 2010, 114, accepted. DOI: 10.1021/jp105422a
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