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DIRECTOR -
X-ray
Crystallography Center
Dr. Kenneth I.
Hardcastle
Facilities Director
Crystallography Lab, Emory University
email: KHardca@emory.edu
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EDUCATION
1952
A.B., San Jose State College
1954
M.S., University of Mississippi
1961
Ph.D., University of Southern California
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PROFESSIONAL EXPERIENCE
1999-present Director, X-ray
Crystallograpy Center, Emory University
1963
- 1999
Professor, California State University Northridge
1994
- 2000
Visiting Faculty, California Institute of Technology
1994
- 1995
Director, Small Molecule X-Ray Lab, Beckman Institute, Caltech
1994
Visiting Faculty, University of Bern, Bern, Switzerland
1985
Visiting Faculty, University College London, England
1977
NSF Faculty Fellowship, Atomics International, Canoga Park, CA
1974
Visiting Faculty, University of Sussex, Brighton, England
1971-1972
NSF Science Faculty Fellow, MIT, Cambridge, MA
1961-1963
Post-Doctoral Fellow, Tufts University, Medford, MA
1954-1956
Chemist, Peninsula Laboratories, Mt. View, CA
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AWARDS
2003-2006 NATO
Research Grant, with Mauro Botta, Universita di Torino, Italy
1998-2000 NATO
Research Grant, with Mauro Botta, Universita di Torino, Italy
1996
PRF Postdoctoral Fellow, with Jay Siegel
, UCSD
1987-1992
NATO Research Grant, with Tony Deeming, University College, London, UK
1983
Fulbright Fellow, U. Parma, Parma, Italy
1971-1972
Science Faculty Fellow, with Al Cotton, MIT
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RECENT PUBLICATIONS
"Cobalt-Templated
Radical Processes: Inter- and Intramolecular Coupling of Propargyl Radicals,"
J. Organomet. Chem., 578, 68-75, 1999, Melikyan, G., Deravakian, A.*,
Myer, S.**, Yadegar, S.**, Hardcastle, K. I., Ciurash, J.** and Toure,
P.*
“Electron
deficient bonding of benzoheterocycles to triosmium clusters: synthesis and
applications to organic chemistry,” Coor. Chem.
Rev., 190-192, 975-1002, 1999, Abedin, Md. J., Bergman, B., Holmquist, R.,
Smith, R., Rosenberg, E., Ciurash, J.**, Roe, J.*, Vazquez, V.*, Ross, C.*,
Kabir, S., Roy, B., Alam, S., Azam, K.A. and Hardcastle, K.I.
"Stereochemistry
of Congested Cyclophanes Containing Chiral Spirobiindanol Phosphonates: X-ray
Structure, HPLC Enantioresolution and Clathration Properties," Eur. J. Org.
Chem., 2799-2806, 1999, Consiglio, G.A., Finocchiaro, P., Failla, S., Ross,
C., Caccamese, S., Giudice, G. and Hardcastle, K.I.
"Experimental
Evidence for a Second Coordination Sphere Water Molecule in the Hydration
Structure of YbDTPA-. Insights for a Re-Assessment of the Relaxivity Data
of GdDTPA," Eur. J.
Inorg.Chem., 2000, 971-977, Hardcastle, K.I., Botta, M., Fasano, M. and
Digilio, G.
"Manganese
(II) / (III) glycolates: preparation, X-ray crystallographic studies and
application in radical cycloaddition reactions," Inorg. Chimica
Acta, 2000, 308, 45-50, Melikyan, G., Amiryan, F.*, Visi, M.*, B. Bales and
Hardcastle, K.I.
“Phenyl/Pentafluorophenyl
Interactions and the Generation of Ordered Mixed Crystals: sym-Triphenethynylbenzene
and sym-Tris(perfluorophenethynyl)benzene,”, Angew. Chem.2000,
39(13) 2323-2325, Ponzini, R., Zagha, R.**, Siegel, J. and Hardcastle, K.I.
“Carboxylation
of a u3-Methylidyne Ligand from a u3-Diazo Methylidyne Triosmium Cluster,”
Organomet. 2000, 18, 3519-3527, Abedin, S. M. T.**, Hardcastle, K. I., Kabir, S.
E., Malik, K. M. A., Matalib, A.,** E. Rosenberg and Abedin, J.**
“Synthesis
of Oxepanes and trans-Fused Bisoxepanes via Biomimetic, endo-Regioselective
Tandem Oxacyclizations of Polyepoxides,” Org. Lett., 2000, 18, 2917-2919,
McDonald, F. E., Wang, X., Do, B. and Hardcastle, K. I.
“Trinuclear
Copper(I)-bipyridine Triskellion: Template/Bascule Control of Coordination
Complex Stereochemistry in a Trefoil Know Precursor,” Angew. Chem.
2000, 40, 749-751, Woods, C.R., Benaglia, M. Toyota, S., Hardcastle, K. and Siegel, J.
S.
“Tetranuclear
Copper(I)-bisphenanthroline Gridwork: Violation of the Principle of
Maximal Donor Coordination Caused by Intercalation and CH-to-N Forces,” Angew. Chem. 2000,
40, 751-752, Toyota, S., Woods, C. R., Benaglia, M.,
Haldimann, R.,Wärnmark, K., Hardcastle, K. and Siegel, J. S.;
"Asymmetric
Sandwich-Type Polyoxoanions. Synthesis, Characterization and X-ray Crystal
Structures of Diferric Complexes," Inorg. Chem., 2001, 39,2323, T.
Anderson, K. I. Hardcastle, N. Okun and C. Hill.
"Experimental
and Computational Studies of Nucleophilic Attack, Tautomerization, and
Hydride Migration in Benzoheterocycle Triosmium Clusters"
Musaev, D. G.; Nowroozi-Isfahani, T.; Morokuma, K.; Abedin, J.; Rosenberg,
E.; Hardcastle, K. I.
Organometallics; (Article); 2006; 25(1); 203-213.
"Reduced Fluorescence Quenching of Cyclodextrin-Acetylene
Dye Rotaxanes"
Park, J. S.; Wilson, J. N.; Hardcastle, K. I.; Bunz, U. H. F.; Srinivasarao,
M.
J. Am. Chem. Soc.; (Communication); 2006; 128(24); 7714-7715
"A Thiadiazole-Fused N,N-Dihydroquinoxaline:
Antiaromatic but Isolable"
Miao, S.; Schleyer, P. v. R.; Wu, J. I.; Hardcastle, K. I.; Bunz, U. H.
F.
Org. Lett.; (Letter); 2007; 9(6); 1073-1076.
"Total Syntheses of Durgamone, Nakorone,
and Abudinol B via Biomimetic Oxa- and Carbacyclizations"
Tong, R.; Valentine, J. C.; McDonald, F. E.; Cao, R.; Fang, X.; Hardcastle,
K. I.
J. Am. Chem. Soc.; (Communication); 2007; 129(5); 1050-1051
Revised:
October 1, 2008
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